Research Interests
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Single molecular chiral recognition on metal surfaces
Chiral recognition at the single molecular level is a fundamental aspect in molecular biophysics and of central importance in the pharmaceutical industry. I am interested in the fundamental mechanism of single-molecular chiral recognition of planar-organic molecules with hydrogen bonding on metal surfaces. Recently, I developed a theoretical model to explain the chiral recognition of PVBA on Ag(111), but not on the Pd(111) observed by UHV STM. The substrate-adsorbate interaction is found to be important in deciding the chiral recognition of PVBA on both Pd (111) and Ag(111).
- B.I. Kim , “Chiral Recognition of a Single Chiral Molecule PVBA on Ag(111) and Pd(111)”, Langmuir (Accepted) ( PDF)
- B.I. Kim , C. Cai, X. Deng, S. S. Perry, “Adsorption-Induced Chirality Influences Surface Orientation in Organic Self-Assembled Structures: an STM Study of PVBA on Pd(111)”, Surf. Sci. 538, 45(2003). ( PDF)
- Molecular scale investigation of bioactive surfaces
Single-molecular manipulation of proteins using smart (dynamically-controllable) surfaces is critical in biomaterials-based therapies. I am interested in unraveling the factors that control complex functions (i.e. protein transport, separation and detection) using photo and thermal activation by scanning-probe microscopy. In my former research group at Sandia, in collaboration with Arizona State University, I was involved in realizing the switchable and reversible control of interfacial interactions between proteins and biomolecular interfaces in complex biological fluids using photo and thermal activation. Specifically I studied the fundamental mechanisms for adsorption and desorption of proteins on a switchable bio-active surface in aqueous solutions using IFM. The successful research remarkably impact methods to functionalize the surfaces of micro-channels and micro-fluidic devices.
- B. C. Bunker, B. I. Kim, J. E. Houston, S. T. Picraux, R. Rosario, A. A. Garcia, M. Hayes, and D. Gust, “ Direct Observations of Photo-Switching in Tethered Spiropyrans Using the Interfacial Force Microscope,” Nano Letters 3, 1723(2003). ( PDF)
- D. L. Huber, R. P. Maginell, M. A. Samara, B.I. Kim, and B. C. Bunker, “ Programmed Adsorption and Release of Proteins in a Microfluidic Device”, Science 301, 352(2003). ( PDF) Related News Article
- Interfacial water structure and its application
Water is a pervasive environmental component whose interactions with surfaces are critical to system performance in a wide range of emerging nanotechnologies. I am interested in studying the water structure in local and confined spaces, which is extremely important for understanding interfacial phenomena in water at nanometer scales. I am also interested in applying this understanding to water-based-nanolithography.
- B. I. Kim , U. H. Pi, S. Yoon and Z. G. Khim, “ Lithography by Tapping Mode Atomic Force Microscope with Electrostatic Force Modulation”, Appl. Phys. A 66, S95(1998).
- B. I. Kim , J. W. Hong, G. T. Jeong, S. H. Moon, D. H. Lee, T. U. Shim and Z. G. Khim, “ Effect of Mg(OH) 2 On YBa 2Cu 3 O 7 Thin Film on MgO Substrate Studied by Atomic Force Microscope”, J. Vac. Sci. Technol. B12(3), 1631(1994).
- Nanotribology: chemical modification of interfacial mechanical properties
Control of frictional and interfacial adhesion properties is of extreme importance in saving energy in mechanical systems and developing microelectrical mechanical machines. I am interested in the functionality of the chemical modification of frictional properties with a class of lubricant. Scanning-probe microscopy will provide more opportunities for the fundamental understanding of molecular scale configurations and their interactions. The advantages of this approach include the presence of a single microasperity (the tip), operation in the wearless regime of friction, and the opportunity for the functionalization of both the tip and the surface.
- B. I. Kim , S. Lee, R. L. Guenard, L. C. Fernandez-Torres, S. S. Perry P. Frantz and S. V. Didziulis, “ Chemical Modification of the Interfacial Frictional Properties of Vanadium Carbide Through Ethanol Adsorption”, Surf. Sci.(2001) 481, 185(2001). ( PDF)
- L. C. Fernandez-Torres, B.I. Kim, S. S. Perry, “ The Frictional Response of VC(100) Surfaces: Influence of 1-octanol and 2,2,2-trifluoroethanol Adsorption,” Tribology Letters 15, 43(2003).
- Magnetic-force microscopy of semiconducting magnetic thin films
A major step towards realizing spintronics is the search for an ideal magnetic semiconductor with tunable ferromagnetic behavior over a wide range of doping. I am interested in investigating the effect of carrier manipulations on the behavior of ferromagnetic nano-domains using MFM. I have extensive experience from the construction of MFM to its application to the imaging magnetic domains on magnetic thin film surfaces.
- J. Philip, A. Punnoose, B. I. Kim, K. M. Reddy, S. Layne1, J. O. Holmes, B. Satpati, P. R. Leclair, T. S. Santos and J. S. Moodera, “ Carrier-Controlled Ferromagnetism in Transparent Oxide Semiconductors,” Nature Materials 5, 298-304 (2006) ( PDF). Related News Article
- B. I. Kim , J. W. Hong, J. I. Kye, Z. G. Khim and S. Yoon, “ Construction of Magnetic Force Microscope and its Application to Magnetic Multilayer Films,” J. Kor. Phys. Soc. 31, S79 (1997).
- R apid detection and analysis of bio-molecular interactions
Combining new experimental techniques with nanoscale bio-organic self-assembled materials will produce ample opportunities to explore new bio-chemical phenomena and may impact future technologies. I am interested in combining state-of-the-art communication skills and nano-mechanical systems for the rapid detection and analysis of bio-molecular interactions. For simple bio-sensing and actuation applications using nanomechanics, I would like to use a cantilever of the scanning-probe system with phase coherent techniques to provide enhanced sensitivity.
- B.I. Kim , “ Direct Comparison between Phase Locked Oscillator and Direct Resonance Oscillator in the Noncontact Atomic Force Microscopy under Ultrahigh Vacuum,” Rev. Sci. Inst. 71, 5035 (2004). (PDF)
- J. W. Hong, B.I. Kim, J. I. Kye and Z.G. Khim, “ Effect of Electrostatic Force and Tapping Mode Operation of Atomic Force Microscope,” J. Kor. Phys. Soc. 31, S83 (1997).