Adam Colson, Ph.D.
Office: SCNC 322
Phone: (208) 426-1063
Research focus: synthetic inorganic and organometallic chemistry; electroactive materials with applications in energy storage and delivery, molecular electronics, and catalysis
2012: Rice University, Ph.D.
2009: Rice University, M.A.
2007: Idaho State University, B.S.
9. Millard, S.; Fothergill, J. W.; Anderson, Z.; Brown, E. C.; King, M. D.; Colson, A. C. “Supramolecular Interactions of Group VI Metal Carbonyl Complexes: The Facilitating Role of 1,3-Bis(p-isocyanophenyl)urea” Inorg. Chem. 2019, 58, 8130-8139.
8. Elsberg, J.G.; Spiropulos, N.G.; Colson, A.C.; Brown, E.C. “Crystal structure of a homoleptic zinc(II) complex based on bis(3,5-diisopropylpyrazol-1-yl)acetate” Acta Crystallogr., Sect. E. 2018, 74, 1259-1262.
7. Leitner, A.P.; Schipper, D.E.; Chen, J.H.; Colson, A.C.; Rusakova, I.; Rai, B.K.; Morosan, E.; Whitmire, K.H. “Synthesis of Hexagonal FeMnP Thin Films from a Single-Source Molecular Precursor” Chem. Eur. J. 2017, 23, 5565-5572.
6. Margulieux, K.R.; Sun, C.; Kihara, M.T.; Colson, A.C.; Zakharov, L.N.; Whitmire, K.H.; Holland, A.W.; Pak, J.J. “Synthesis and Characterization of Bimetallic Single-Source Precursors (Ph3P)2M(μ-SEt)2E(SEt)2 for MES2 Chalcopyrite Materials (M = Cu, Ag and E = In, Ga, Al)” Eur. J. Inorg. Chem. 2017, 13, 2068-2077.
5. Colson, A.C.; Chen, C.W.; Morosan, E.; Whitmire, K.H. “Synthesis of Phase-Pure Ferromagnetic Fe3P Films from Single-Source Molecular Precursors” Adv. Funct. Mater. 2012, 22, 1850-1855.
4. Colson, A.C.; Whitmire, K.H. “Synthesis of Fe2-xMnxP Nanoparticles from Single-Source Molecular Precursors” Chem. Mater. 2011, 23, 3731-3739.
3. Stavila, V.; Bulimestru, I.; Gulea, A.; Colson, A.C.; Whitmire, K.H. “Hexaaquacobalt(II) and hexaaquanickel(II) bis(-pyridine-2,6-dicarboxylato)bis[(pyridine-2,6-dicarboxylato)bismuthate(III)] dihydrate” Acta Crystallogr., Sect. C. 2011, C67, m65-m68.
2. Mandal, T.; Piburn, G.; Stavila, V.; Rusakova, I.; Ould-Ely, T.; Colson, A.C.; Whitmire, K.H. “New Mixed Ligand Single-Source Precursors for PbS Nanoparticles and Their Solvothermal Decomposition to Anisotropic Nano- and Microstructures” Chem. Mater. 2011, 23, 4158-4169.
1. Colson, A.C.; Whitmire, K.H. “Synthesis, Characterization, and Reactivity of the Heterometallic Dinuclear μ-PH2 and μ-PPhH Complexes FeMn(CO)8(μ-PH2) and FeMn(CO)8(μ-PPhH)” Organometallics. 2010, 29, 4611-4618.
The Colson group investigates the synthesis and physical properties of metal carbonyl clusters. Metal carbonyl clusters—or MCCs—are molecular species consisting of multiple transition metal nuclei stabilized by carbon monoxide ligands. MCCs possess distinctive structural and electronic properties, including the ability to undergo multiple electrochemical reduction events without experiencing decomposition. Although this “electron reservoir” behavior has potential applications in electronic devices or energy systems, the synthetic methods used to produce MCCs are often poorly-selective and can result in broad and unpredictable product distributions. As an alternative approach, we are interested in studying non-covalent interactions that might drive the self-assembly of MCC species. Students in the Colson lab are trained to handle air- and moisture-sensitive compounds using specialized glassware and laboratory techniques. Student researchers also gain experience in a wide variety of analytical techniques, including nuclear magnetic resonance spectroscopy, infrared spectroscopy, mass spectrometry, X-ray diffraction, and electrochemical methods.