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Research

Pillar 1: Smart Materials

Magnetostrictive Materials

Magnetostrictive materials deform in response to a magnetic field or exhibit changes in magnetization when stressed. Our group focuses on certain magnetostrictive materials, including terbium–iron–dysprosium (Terfenol-D), iron–gallium (Galfenol), iron–cobalt–vanadium (Remendur), and cobalt ferrites. Leveraging their unique properties, we have pursued applications such as:

  1. Magnetically-activated bioscaffolds for bone tissue engineering (NSF CAREER)
  2. Acoustic transducers for pipeline structural health monitoring (DOE CINR)
  3. Ultrasonic waveguide thermometers for nuclear power plants (DOE ASI program)

Piezoelectric Materials

Piezoelectric materials undergo significant deformation instantaneously when subjected to an electrical field. Conversely, they generate electric charges on their surfaces when exposed to mechanical stress. Our group focuses on certain piezoelectric materials, including polyvinylidene fluoride polymer (PVDF), poly(vinylidene fluoride-co-trifluoroethylene) polymer (PVDF-trFE), aluminum nitride (AlN), lithium niobate (LNO), and barium titanate (BTO). We have explored applications such as

  1. Dual-mode sensors for structural health monitoring in inflatable habitats (NASA EPSCoR)
  2. Flexible and stretchable tactile senor arrays for human health monitoring (NASA ISGC Fellowship & NIH COBRE RPL)
  3. Surface acoustic wave thermometers for nuclear power plants (DOE ASI)

Shape Memory Materials

Shape memory materials can recover a predetermined permanent shape after being deformed into a temporary shape. This shape memory effect can be triggered by external stimuli including heat, light, or electricity.  Our group focuses on PLA/TPU composites and biocompatible TATATO/TMTMP-based polymers. We have investigated applications such as:

  1. Flexible and morphing electronics for deep space exploration (NASA EPSCoR)
  2. Self-activated neural stimulators (Boise State)

Pillar 2: Additive Manufacturing

Aerosol Jet Printing

Aerosol jet printing (AJP) involves atomizing a nanoparticle colloid ink into a fine aerosol, which is carried by a gas stream (typically nitrogen) through a nozzle and precisely deposited onto a substrate. This technique enables high-resolution printing of complex patterns on both flat and three-dimensional surfaces without requiring masks. In addition to passive electronic materials such as silver, gold, and nickel, our group has successfully used AJP to print the following smart materials:

  1. Terfenol-D
  2. Galfenol
  3. Lithium Niobate

Coupled with a pulsed light sintering system (Xenon S2100) or a helium plasma sintering system, we have achieved room-temperature sintering of smart materials, enabling AJP on temperature-sensitive substrates such as human skin and plastics.

(a) Schematic of the AJP process and (b) our commercial Optomec tabletop aerosol jet printer.
(a) Schematic of the AJP process and (b) our commercial Optomec tabletop aerosol jet printer.

Material Extrusion

Material extrusion (MEX) is an additive manufacturing process in which viscous pastes or molten filaments are extruded through a nozzle, layer by layer, to build three-dimensional structures. This technique enables the fabrication of complex geometries with precise control over material placement. Our lab operates a custom fused filament fabrication system capable of printing metal filaments (e.g., stainless steel 17-4 and copper), two Hyrel MEX systems, and has access to an nScrypt MEX system for high-precision ink deposition. Using these platforms, we have successfully printed the following smart materials:

  1. Cobalt ferrite
  2. Terfenol-D
  3. Galfenol
  4. PVDF-trFE
  5. Barium titanate/PDMS composites
  6. Terfenol-D/PVDF composites
  7. PLA/TPU shape memory composites

Each Hyrel system is equipped with five docking stations that support interchangeable extrusion and processing heads—including fused filament, pneumatic, stepper-motor-driven, and laser heads—enabling versatile multi-material printing. This capability allows us to integrate printed smart materials with flexible electronic components made from liquid metals, laser-induced graphene, silver pastes, PEDOT:PSS, and liquid metal composites.

(a) Hyrel HR MEX system, (b) Nordson EFD pneumatic extruder, and (c) nScrypt 150-3Dn-HP MEX system.
(a) Hyrel HR MEX system, (b) Nordson EFD pneumatic extruder, and (c) nScrypt 150-3Dn-HP MEX system.

Acoustic Droplet Ejection

Acoustic droplet ejection (ADE) is a non-contact printing and dispensing technique that uses focused acoustic energy to eject precise droplets of liquid from a source reservoir onto a target surface. By tuning the acoustic wave frequency and energy, ADE can generate droplets ranging from picoliters to nanoliters without the need for nozzles or physical contact. This eliminates risks of clogging, contamination, or mechanical wear, making it especially advantageous for handling viscous, delicate, or biologically sensitive fluids. Our group has customized an ADE system and is exploring its capabilities in printing magnetostrictive thin films.

A custom acoustic droplet ejection printing system developed by the SMSL.
A custom acoustic droplet ejection printing system developed by the SMSL.

Pillar 3: Multiphysics and Multiscale Modeling

Multiscale Constitutive Modeling

Printed smart materials, particularly metals and ceramics, demand intensive multiscale modeling to accurately describe their behavior. The figure below illustrates a typical microstructure of a magnetostrictive acoustic transducer. A robust constitutive model must capture phenomena across multiple length scales, including magnetic domain rotation at the nanoscale, crystal deformation and porosity at the microscale, and multiphysics interactions at the millimeter to meter scale. While individual models targeting each scale exist in the literature, developing a comprehensive framework that bridges these scales remains a significant challenge. Leveraging the Mori–Tanaka homogenization method and representative volume element concepts, our group has developed efficient and accurate constitutive models for the following printed smart materials:

  1. Terfenol-D composites
  2. Terfenol-D/PVDF composites
  3. Monolithic Terfenol-D
A schematic showing the multiscale modeling needs for the printed magnetostrictive devices.
A schematic showing the multiscale modeling needs for the printed magnetostrictive devices.

Multiphysics Finite Element Modeling

Smart materials and systems are multiphysics in nature. For instance, the linear variable differential transformer (LVDT) used in nuclear reactors involves electrical dynamics, magnetic dynamics, mechanical dynamics, and thermal dynamics. A comprehensive system-level model needs to account for individual dynamics and their coupling. Our team has successfully developed and validated the following multiphysics models for smart materials and systems:

  1. Magnetostrictive waveguide thermometers
  2. Piezoelectric surface acoustic wave thermometers
  3. Linear variable differential transformers
  4. PLA/TPU-based shape memory morphing electronics
  5. Magnetostrictive unimorph actuators
Linear Variable Differential Transformers (LVDT) sensors
(a) A CT image showing the cross section of a Halden LVDT sensor. (b) 2D axisymmetric model configuration in COMSOL Mutiphysics. (c) Magnitude of magnetic flux density in Tesla when the core is 1 mm away from the null position.

Research Spotlights

Ongoing Projects

Project 1 – Printed Magnetoelectric Composites as a Bioscaffold for Bone Tissue Engineering (NSF CAREER)

We aim to revolutionize bone defect treatment by developing a transformative magnetoelectric biomaterial replicating the complex mechanobiological environments in human bones. This functional biomaterial, made of magnetostrictive Terfenol-D nanoparticles dispersed in a piezoelectric PVDF polymer matrix, can generate precise, nonintrusive mechanical cues through two unique mechanisms: the Delta-E effect, mimicking elasticity variations during bone growth, and the magnetoelectric effect, mimicking mechanical vibrations and piezoelectric stimuli found in bones.

Process diagram showing bioscaffold synthesis, extrusion, magneto-mechanical testing, and in vitro cell results with microscopy images of proliferation and osteogenesis.
Summary of research objectives. Printing bone-mimicking Terfenol-D/PVDF bioscaffolds (R1). Controlling MSC proliferation and differentiation via the Delta E effect (R2) and the magnetoelectric effect (R3).

Project 2 – Magnetostrictive Guided-Wave Transducers for Nuclear Reactor Piping System Monitoring (DOE CINR)

A 2016 report revealed that 80% of operational nuclear power plants in the U.S. experienced financial challenges or faced early retirement, primarily because their maintenance costs are three to four times higher than those of coal or natural gas plants. Among the most vulnerable components are reactor piping systems, which undergo significant wear and degradation from environmental stressors, requiring timely maintenance. To address these challenges and close existing research gaps, we are developing a novel magnetostrictive structural health monitoring (SHM) system specifically designed for in-pile applications. The figure below highlights our recent progress in room-temperature printing of magnetostrictive thin films.

AJP and photonic sintering of Terfenol-D thin films.
AJP and photonic sintering of Terfenol-D thin films.

Another figure illustrates the configuration of the magnetostrictive Lamb wave transducer and demonstrates that its performance is comparable to commercial PZT transducers.

(a) Schematic and (b) physical assembly of Galfenol-based Lamb wave transducer. (c) Comparison of Galfenol and commercial PZT transducers.
(a) Schematic and (b) physical assembly of Galfenol-based Lamb wave transducer. (c) Comparison of Galfenol and commercial PZT transducers.

Project 3 – On-Demand Manufacturing of Smart Systems for Structural Health Monitoring (NASA EPSCoR)

Inflatable reentry vehicles and habitats are attractive for NASA’s Moon to Mars Exploration campaign and the next-generation space station, because of their high volume-to-mass ratio and packaging efficiency. Since inflatable structures are usually thin-walled, ionizing radiation and micro-meteoroid orbital debris pose considerable threats to their integrity. To meet this urgent structural health monitoring needs, we aim to combine smart materials development and On-Demand Manufacturing of Electronics (ODME) techniques to deliver a wireless, flexible, self-sustaining, and multifunctional SHM system. We have first developed a sensor features a PVDF-trFE film sandwiched between two electrodes, enabling dual-mode operation. In piezoresistive mode, resistance changes in the printed meandering electrode reflect accumulated strain. In piezoelectric mode, the PVDF-TrFE film generates voltage in response to dynamic impacts.

Piezoresistive and piezoelectric dual-mode sensor for inflatable structures.
Piezoresistive and piezoelectric dual-mode sensor for inflatable structures.

Our group has successfully printed magnetostrictive composites on top of passive substrates to form cantilever actuators, also known as unimorph actuators, as shown in the figure below. When a magnetic field is applied along the longitudinal direction of the beam, the magnetostrictive layer deforms while the passive substrate tends to maintain flat. Therefore, the unimorph actuator outputs micro-scale and butterfly-shape tip deflection. This actuator can be potentially used for precision drug delivery or optical instrument control.

msm-actuator
(a) Configuration of magnetostrictive beam actuator, (b) magnetostrictive cobalt-ferrite beam printed by our nScrupt MEX system; and (c) Tip deflection of the cobalt ferrite beam under varying magnetic field.

Furthermore, we have printed PLA/TPU composites into morphing structures (see figure below) that can be activated by external heating. By integrating these composites with electrically conductive traces, we achieved electrical activation of the shape memory structures. In addition, by adjusting the composite color, we enabled light-based activation.

printed shape memory polymer
Printed shape memory polymers morphing between a 3D rose shape and a 2D Bronco logo.

Project 4 – Magnetostrictive Waveguide Thermometers for Nuclear Power Plants (DOE ASI)

Ultrasonic thermometry has the potential to improve upon temperature sensors currently used for in-core temperature measurements. Ultrasonic thermometers (UTs) work on the principle that the speed at which sound travels through a material (acoustic velocity) is dependent on the temperature of the material. Temperature may be derived by introducing a short acoustic pulse to the sensor and measuring the time delay of acoustic reflections generated at acoustic discontinuities along the length of the sensor. UT temperature measurements may be made near the melting point of the sensor material, allowing monitoring of temperatures potentially in excess of 3000 °C. The figure below shows a typical UT design based on iron-gallium alloys or Galfenol. We have developed an accurate and efficient multiphysics model that is able to capture the acoustic wave propagation in the waveguide.

(a) Physical assembly of magnetostrictive waveguide thermometer. (b) Laser vibrometry and (c) output voltage measurement from the waveguide. (d) Finite element simulation of the magnetostrictive waveguide.
(a) Physical assembly of magnetostrictive waveguide thermometer. (b) Laser vibrometry and (c) output voltage measurement from the waveguide. (d) Finite element simulation of the magnetostrictive waveguide.

Selected Completed Projects

Printed Piezoelectric Surface Acoustic Wave (SAW) Thermometer for Nuclear Power Plants

Surface acoustic wave (SAW) devices are a subclass of micro-electromechanical systems (MEMS) that generate an acoustic emission when electrically stimulated. These transducers also work as detectors, converting surface strain into readable electrical signals. Physical properties of the generated SAW are material dependent and influenced by external factors like temperature. By monitoring temperature-dependent scattering parameters a SAW device can function as a thermometer to elucidate substrate temperature. Traditional fabrication of SAW sensors requires labor- and cost- intensive subtractive processes that produce large volumes of hazardous waste. We utilize an innovative aerosol jet printer to directly write consistent, high-resolution, silver comb electrodes onto a Y-cut LiNbO3 substrate. The printed, two-port, 20 MHz SAW sensor exhibited excellent linearity and repeatability while being verified as a thermometer from 25 to 200 ∘C. Our journal paper entitled “Aerosol jet printing of piezoelectric surface acoustic wave thermometer” won the the Office of Nuclear Energy, U.S. Department of Energy’s Innovations in Nuclear Energy Research Development Student Award of Excellence in 2024.
(a) AJP-printed surface acoustic wave thermometer. (b) Surface profilometry of the AJP-printed silver traces. (c) Thermometer performance up to 200 Celsius.
(a) AJP-printed surface acoustic wave thermometer. (b) Surface profilometry of the AJP-printed silver traces. (c) Thermometer performance up to 200 Celsius.

Multiphysics Modeling of Surface Acoustic Wave (SAW) Transducers

Our team developed a series of temperature-dependent finite element models for a SAW transducer consisting of printed silver interdigitated transducers (IDTs) deposited onto piezoelectric lithium niobate. A time-domain study enabled visualization of the wave propagation and successfully guided the denoising of the scattering parameter measurement. Additionally, frequency-domain models using traditional modal analysis or the unique port boundary condition feature in COMSOL Multiphysics accurately predicted the temperature-driven natural frequency drift in the SAW thermometer. The finite element models developed in this study serve to facilitate the computer-aided design of future SAW transducers for applications in harsh environments.
Composite image showing lithium niobate research. Left: photo of silver pulser and receiver IDTs on a Y-cut lithium niobate substrate, with 1 mm scale and a 3D surface profile map. Middle: two diagrams illustrating electrode placement—one cross-sectional, one 3D. Right: stress distribution graph in MPa, and a frequency response chart comparing experimental vs. simulation S21 values.

Constitutive Modeling of Printed Terfenol-D Composites

In collaboration with National Cheng Kung University, we developed a mathematical model for magnetostrictive composites made of Terfenol-D particles embedded in a polymer matrix. The model accounts for particle orientation, size, and volume fraction, as well as mechanical loads and magnetic fields. Unlike most existing models, which only consider particle orientation at the composite level, our approach incorporates it directly at the particle level. This makes the framework both more efficient and equally accurate, as confirmed by comparisons with published experimental data.

Sponsors and Collaborators

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NSF
United States of America Department of Energy
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